Class 12 Chemistry Solutions MCQs With Answer

Class 12 chemistry MCQs with answers are provided here for Solutions. These MCQs are based on the CBSE board curriculum and correspond to the most recent Class 12 chemistry syllabus. By practicing these Class 12 Multiple choice questions, students will be able to quickly review all of the ideas covered in the chapter and prepare for the Class 12 Annual examinations as well as other entrance exams such as NEET and JEE.

Class 12 Chemistry Solutions MCQs With Answer

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Q3. At a given temperature, osmotic pressure of a concentrated solution of a substance _.

  1. Is higher than that at a dilute solution.
  2. Is lower than that of a dilute solution.
  3. Is same as that of a dilute solution.
  4. Cannot be compared with osmotic pressure of dilute solution.
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Ans: 1. Is higher than that at a dilute solution.

Q4. At equilibrium the rate of dissolution of a solid solute in a volatile liquid solvent is __.

  1. Less than the rate of crystallisation.
  2. Greater than the rate of crystallisation.
  3. Equal to the rate of crystallisation.
  4. Zero.
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Ans: 3. Equal to the rate of crystallisation.

Explanation:
This happens as per conditions attained at equilibrium state; i.e. rate of forward reaction (dissolution) = rate of backward reaction
(crystallisation)

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Q8. Considering the formation, breaking and strength of hydrogen bond, predict which of the following mixtures will
show a positive deviation from Raoult’s law?

  1. Methanol and acetone.
  2. Chloroform and acetone.
  3. Nitric acid and water.
  4. Phenol and aniline.
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Ans: 1. Methanol and acetone.

Explanation:
Mixture of Methanol and acetone shows positive deviation because methanol-methanol and acetone-acetone interactions are more
than methanol-acetone. The more number of hydrogen bonds are broken the less number of new H-bonds are formed.

Q9. If two liquids A and B form minimum boiling azeotrope at some specific composition then __.

  1. A–B interactions are stronger than those between A–A or B–B.
  2. vapour pressure of solution increases because more number of molecules of liquids A and B can escapefrom the solution.
  3. vapour pressure of solution decreases because less number of molecules of only one of the liquids escape
    from the solution.
  4. A–B interactions are weaker than those between A–A or B–B.
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Ans: 4. A–B interactions are weaker than those between A–A or B–B.


Explanation:

  1. The solutions which show large positive deviation from Rault’s law form minimum boiling azeotrope at some specific composition.
  2. In case of positive deviation from Rault’s law A-B interactions are weaker than those between A–A or B–B.

Q10. Relative lowering of vapour pressure is a colligative property because__________.

  1. It depends on the concentration of a non electrolyte solute in solution and does not depend on the nature
    of the solute molecules.
  2. It depends on number of particles of electrolyte solute in solution and does not depend on the nature of
    the solute particles.
  3. It depends on the concentration of a non electrolyte solute in solution as well as on the nature of the solute
    molecules.
  4. It depends on the concentration of an electrolyte or non electrolyte solute in solution as well as on the
    nature of solute molecules.
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Ans: 1. It depends on the concentration of a non electrolyte solute in solution and does not depend on the nature of the solute molecules.

  1. It depends on number of particles of electrolyte solute in solution and does not depend on the nature of the solute particles.

Q11. On the basis of information given below mark the correct option.
Information:

  1. In bromoethane and chloroethane mixture intermolecular interactions of A–A and B–B type are nearly same
    as A–B type interactions.
  2. In ethanol and acetone mixture A–A or B–B type intermolecular interactions are stronger than A–B type
    interactions.
  3. In chloroform and acetone mixture A–A or B–B type intermolecular interactions are weaker than A–B type
    interactions.
  1. Solution (B) and (C) will follow Raoult’s law.
  2. Solution (A) will follow Raoult’s law.
  3. Solution (B) will show negative deviation from Raoult’s law.
  4. Solution (C) will show positive deviation from Raoult’s law.
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Ans: 2. Solution (A) will follow Raoult’s law.

Explanation:
For an ideal solution A-A and B-Bintermolecular interactions should be nearly same as A-B type interactions

Q12. Which of the following binary mixtures will have same composition in liquid and vapour phase?

  1. Benzene-Toluene.
  2. Water-Nitric acid.
  3. Water-Ethanol.
  4. n-Hexane -n-Heptane.
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Ans: 2. Water-Nitric acid.

  1. Water-Ethanol.
    Explanation:
    Non-ideal solution mixtures with same composition in liquid and vapour phase are azeotropes. Water-nitric acid has maximum boiling
    azeotrope and water-ethanol has a minimum boiling azeotrope.

Q13. Which of the following factor (s) affect the solubility of a gaseous solute in the fixed volume of liquid solvent?
(a) Nature of solute (b) Temperature (c) Pressure

  1. (a) and (c) at constant T.
  2. (a) and (b) at constant P.
  3. (b) and (c) only.
  4. (c) only.
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Ans: 1. (a) and (c) at constant T.

  1. (a) and (b) at constant P.
    Explanation:
    At constant temperature, the solubility of a gaseous solute in liquid depends on nature of solute and pressure. At constant pressure,
    solubility is dependent upon nature of solute and temperature.

Q14. In comparison to a 0.01M solution of glucose, the depression in freezing point of a 0.01M MgCl solution is
__.

  1. The same.
  2. About twice.
  3. About three times.
  4. About six times.
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Ans: 3. About three times.

Q15. A beaker contains a solution of substance ‘A’. Precipitation of substance ‘A’ takes place when small amount of ‘A’ is
added to the solution. The solution is _.

  1. Saturated.
  2. Supersaturated.
  3. Unsaturated.
  4. Concentrated.
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Ans: 2. Supersaturated.
Explanation:
When small amount of solute is added to its solution and it does not dissolve and get precipitated then this solution is supersaturated
solution.

Q16. Maximum amount of a solid solute that can be dissolved in a specified amount of a given liquid solvent does not
depend upon _.

  1. Temperature.
  2. Nature of solute.
  3. Pressure.
  4. Nature of solvent.
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Ans: 3. Pressure.
Explanation:
Solubility of a solid in liquid does not depend upon pressure since solid and liquids are almost incompressible

.

Q17. Low concentration of oxygen in the blood and tissues of people living at high altitude is due to __.

  1. Low temperature.
  2. Low atmospheric pressure.
  3. High atmospheric pressure.
  4. Both low temperature and high atmospheric pressure.
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Ans: 2. Low atmospheric pressure.

Explanation:
At high altitude the atmospheric pressure is decreased &, due to low atmospheric pressure the solubility of oxygen in blood and
tissues is reduced.

Q18. Colligative properties depend on __.

  1. The nature of the solute particles dissolved in solution.
  2. The number of solute particles in solution.
  3. The physical properties of the solute particles dissolved in solution.
  4. The nature of solvent particles.
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Ans: 2. The number of solute particles in solution.
Explanation:
Colligative properties depend upon the number of solute particles in the solution and independent of its nature.

Q19. 4L of 0.02M aqueous solution of NaCl was diluted by adding one litre of water. The molality of the resultant
solution is __.

  1. 0.004
  2. 0.008
  3. 0.012
  4. 0.016
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Ans: 4. 0.016

Q20. An unripe mango placed in a concentrated salt solution to prepare pickle, shrivels because _.

  1. It gains water due to osmosis.
  2. It loses water due to reverse osmosis.
  3. It gains water due to reverse osmosis.
  4. It loses water due to osmosis.
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Ans: 4. It loses water due to osmosis.
Explanation:
Water starts moving out of mango (lower concentration) to the salt solution (higher concentration) due to osmosis.