Class 12 Chemistry Haloalkanes and Haloarenes MCQs with Answer
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Q3. In these questions, a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices.
- Assertion and reason both are correct statements and reason is correct explanation for assertion.
- Assertion and reason both are correct statements but reason is not correct explanation for assertion.
- Assertion is correct statement but reason is wrong statement.
- Assertion is wrong statement but reason is correct statement.
Assertion: Lower members of alkyl halides are colourless gases.
Reason: Alkyl iodides in general turn black on exposure to air and light.
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Ans: 3. Assertion is correct statement but reason is wrong statement.
Explanation:
Alkyl iodides in general turn brown due to liberation of I on decomposition by the action of air and light.
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Ans: 1. Intermediate (c) is unstable because in this carbon is attached to 5 atoms.
- Intermediate (c) is less stable than the reactant (b).
Explanation:
In the given reaction intermediate (c) is unstable because the carbon atom is attached to 5 atoms and is less stable than reactant (b).
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Ans: 4. (a) < (b) < (c)
Explanation:
Electron withdrawing group increase the reactivity of aryl halides, more is the number of electron withdrawing group,the more is rate towards nucleophilic substitution.
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Q9. Which is the correct increasing order of boiling points of the following compounds?
1-Iodobutane, 1-Bromobutane, 1-Chlorobutane, Butane
1. Butane < 1-Chlorobutane < 1-Bromobutane < 1-Iodobutane
2. 1-Iodobutane < 1-Bromobutane < 1-Chlorobutane < Butane
3. Butane < 1-Iodobutane < 1-Bromobutane < 1-Chlorobutane
4. Butane < 1-Chlorobutane < 1-Iodobutane < 1-Bromobutane
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Q10. Which of the following compounds are gem-dihalides?
- Ethylidene chloride
- Ethylene dichloride
- Methylene chloride
- Benzyl chloride
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Ans: 2. b, c
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Ans: 1. CH2Cl2 .
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